Divergent Synthesis of Quinazolin-4(3H)‑ones and Tryptanthrins Enabled by a tert-Butyl Hydroperoxide/K3PO4‑Promoted Oxidative Cyclization of Isatins at Room Temperature

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成果类型：

期刊论文

作者：

Jia, Feng-Cheng;Zhou, Zhi-Wen;Xu, Cheng;Wu, Yan-Dong*;Wu, An-Xin*（吴安心）

通讯作者：

Wu, Yan-Dong;Wu, An-Xin（吴安心）

作者机构：

[Wu, An-Xin; Jia, Feng-Cheng; Zhou, Zhi-Wen; Xu, Cheng; Wu, Yan-Dong] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.

[Wu, An-Xin] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.

通讯机构：

[Wu, An-Xin] L

[Wu, YD; Wu, AX] C

Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.

Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China.

语种：

英文

期刊：

Organic Letters

ISSN：

1523-7060

年：

2016

卷：

期：

页码：

2942-2945

DOI：

10.1021/acs.orglett.6b01291

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21272085, 21472056]; Central China Normal University [2015YBZD015]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

A synergetic tert-butyl hydroperoxide/K3PO4-promoted oxidative cyclization has been developed for the facile synthesis of various functionalized quinazolin-4(3H)-ones from commercially available isatins and amidine hydrochlorides at room temperature. The synthetic utility of this strategy was illustrated by the convenient synthesis of tryptanthrin derivatives via a self-...

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Divergent Synthesis of Quinazolin-4(3H)‑ones and Tryptanthrins Enabled by a tert-Butyl Hydroperoxide/K3PO4‑Promoted Oxidative Cyclization of Isatins at Room Temperature

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