Here, we report a nickel-catalyzed reductive C(sp3)-C(sp2) cross-coupling of monofluoroalkyl triflates with aryl halides, yielding a series of functionalized monofluoroalkylated arenes. This method is characterized by mild reaction conditions, a broad substrate scope, with excellent functional group compatibility. Facile follow-up transformations highlight its utility as an appealing tool in the synthesis of pharmaceutical derivatives. Here, we report a nickel-catalyzed reductive C(sp3)-C(sp2) cross-coupling of monofluoroalkyl triflates with aryl ha...