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Tracking the environmental fate of fipronil and three of its metabolites in garlic based on sampling rate-corrected in vivo solid phase microextraction combined with gas chromatography-mass spectrometry

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成果类型:
期刊论文
作者:
Chen, Tiantian;Hu, Jiajia;Chen, Yanyan;Liu, Ying;Li, Yan;...
通讯作者:
Xu, Hui
作者机构:
[Liu, Ying; Hu, Jiajia; Li, Yan; Chen, Tiantian; Xu, Hui; Chen, Yanyan] Cent China Normal Univ, Coll Chem, Key Lab Insecticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Xu, Hui] C
Cent China Normal Univ, Coll Chem, Key Lab Insecticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Fipronil;Gas chromatography-mass spectrometry;Invivo solid phase microextraction;Long-term monitoring;Metabolites
期刊:
Analytica Chimica Acta
ISSN:
0003-2670
年:
2022
卷:
1190
页码:
339263
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [22076059, 21675058]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [CCNU18TS006]; International Joint Research Center for Intelligent Biosensing Technology and Health; 111 ProjectMinistry of Education, China - 111 Project [B17019]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, a sampling rate-corrected in vivo solid-phase microextraction-gas chromatography-mass spectrometry method (SR-in vivo SPME-GC-MS) was constructed to simultaneously detect fipronil and three of its metabolites in garlic, and their environmental behavior was long-term monitored in in vivo mode. All of three fipronil metabolites were more difficult to degrade than the parent pesticide. The final degradation rates of the metabolites in garlic were in the range of 4.4%-25.1%, much lower than that of the parent (78.6%-85.8%). While the...

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