Intercepting a labile anti-π-allyl-iridium complex before its isomerization

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成果类型：

期刊论文

作者：

Bao-Le Qu;Mao-Mao Zhang;Liang-Qiu Lu*;Wen-Jing Xiao

通讯作者：

Liang-Qiu Lu

作者机构：

[Bao-Le Qu; Mao-Mao Zhang; Wen-Jing Xiao] CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, China

State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

[Liang-Qiu Lu] CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, China<&wdkj&>State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

通讯机构：

[Liang-Qiu Lu] C

CCNU-uOttawa Joint Research Centre, Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, China<&wdkj&>State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

语种：

英文

期刊：

Chem

ISSN：

2451-9294

年：

2021

卷：

期：

页码：

552-554

DOI：

10.1016/j.chempr.2021.02.022

基金类别：

L.-Q.L. and W.-J.X. acknowledge financial support from the National Natural Science Foundation of China ( 21822103 , 21820102003 , 21772052 , and 21772053 ).

机构署名：

本校为第一机构

院系归属：

化学学院

摘要：

The stereodefined installation of chiral centers adjacent to thermodynamically unstable Z-olefins is a challenge in synthetic chemistry. In a recent work published in Science, You and coworkers reported an iridium-catalyzed, Z-retentive asymmetric allylic allylation with a variety of Z-allyl esters, providing elegant access to important chiral Z-olefins. © 2021The stereodefined installation of chiral centers adjacent to thermodynamically unstable Z-olefins is a challenge in synthetic chemistry. In a recent work published in Science, You and co...

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Intercepting a labile anti-π-allyl-iridium complex before its isomerization

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