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Reactive oxygen species dependent degradation pathway of 4-chlorophenol with Fe@Fe2O3 core–shell nanowires

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成果类型:
期刊论文
作者:
Huang, Qi;Cao, Menghua;Ai, Zhihui;Zhang, Lizhi*
通讯作者:
Zhang, Lizhi
作者机构:
[Cao, Menghua; Zhang, Lizhi; Huang, Qi; Ai, Zhihui] Cent China Normal Univ, Inst Environm Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Inst Environm Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
4-Chlorophenol;Degradation mechanism;Diethylenetriaminepentacetate acid;Molecular oxygen activation;Nanoscale zero-valent iron
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2015
卷:
162
页码:
319-326
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21173093, 21177048]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; self-determined research funds of CCNU from colleges' basic research and operation of MOE
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, an environmentally benign polyaminocarboxylic ligand diethylenetriamine pentacetate (DTPA) was first used to promote the aerobic 4-chlorophenol (4-CP) degradation with Fe@Fe2O3 core-shell nanowires, and then compared with the most used counterpart ethylenediamine tetraacetate (EDTA) of poor biodegradability. Although the 4-CP removal rate in the Fe@Fe2O3/DTPA/Air system was slower owing to the preferential degradation of DTPA, the total organic carbon removal rate in the Fe@Fe2O3/DTPA/4-CP/Air system was much faster than that in ...

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