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An economic bifunctional electrolyte additive for highly reversible zinc anode

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成果类型:
期刊论文
作者:
Wei, Chenchen;Zhou, Yu;Wang, Xiaolong;Qi, Huimin;Li, Xiaohui;...
通讯作者:
Yang, Ze;Yu, Y
作者机构:
[Wang, Wenping; Yu, Ying; Wang, Xiaolong; Zhou, Yu; Li, Xiaohui; Zou, Ting; Qi, Huimin; Yang, Ze; Yang, Z; Wei, Chenchen] Cent China Normal Univ, Inst Nanosci & Nanotechnol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
通讯机构:
[Yu, Y ; Yang, Z] C
Cent China Normal Univ, Inst Nanosci & Nanotechnol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Zinc -ion batteries;Zinc anode;TMP;Organic additives
期刊:
Materials Today Physics
ISSN:
2542-5293
年:
2024
卷:
41
页码:
101356
基金类别:
CRediT authorship contribution statement Chenchen Wei: Writing – original draft, Data curation, Conceptualization. Yu Zhou: Writing – original draft, Investigation. Xiaolong Wang: Formal analysis. Huimin Qi: Formal analysis. Xiaohui Li: Formal analysis. Ting Zou: Formal analysis. Wenping Wang: Formal analysis. Ze Yang: Writing – review & editing, Supervision, Methodology, Conceptualization. Ying Yu: Writing – review & editing, Supervision, acquisition, Conceptualization.
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
Zinc metal batteries (ZMBs) have received a lot of attention due to their high capacity, proper redox potential and low cost. However, zinc anodes suffer from serious dendritic problems and side reactions, resulting in poor cycling stability of zinc ion batteries. Herein, organic additive trimethyl phosphate (TMP) is introduced into inexpensive ZnSO4 electrolyte to stabilize Zn anode. TMP exhibits bifunctional properties in this cost-effective electrolyte system. It prefers adsorbing on (002) plane of zinc which leads to preferential crystal gr...

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