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A photoredox catalyzed iminyl radical-triggered C-C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

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成果类型:
期刊论文
作者:
He, Bin-Qing;Yu, Xiao-Ye;Wang, Peng-Zi;Chen, Jia-Rong*;Xiao, Wen-Jing
通讯作者:
Chen, Jia-Rong
作者机构:
[He, Bin-Qing; Xiao, Wen-Jing; Chen, Jia-Rong; Yu, Xiao-Ye; Wang, Peng-Zi] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, CCNU uOttawa Joint Res Ctr, Minist Educ,Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
[Xiao, Wen-Jing] Huanggang Normal Univ, Hubei Key Lab Proc & Applicat Catalyt Mat, Huanggang 438000, Hubei, Peoples R China.
通讯机构:
[Chen, Jia-Rong] C
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, CCNU uOttawa Joint Res Ctr, Minist Educ,Coll Chem, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
期刊:
Chemical Communications
ISSN:
1359-7345
年:
2018
卷:
54
期:
86
页码:
12262-12265
基金类别:
NNSF of ChinaNational Natural Science Foundation of China (NSFC) [21622201, 21472058, 21472057, 21772053]; Science and Technology Department of Hubei Province [2016CFA050, 2017AHB047]; Program of Introducing Talents of Discipline to Universities of China (111 Program); Program of Introducing Talents of Discipline to Universities of ChinaMinistry of Education, China - 111 Project [B17019]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A photoredox-catalyzed iminyl radical-triggered C-C bond cleavage/addition/Kornblum oxidation cascade of cycloketone oxime esters and styrenes in DMSO is described. This three-component, one-pot procedure features mild conditions, a broad substrate scope, and high functional group tolerance, providing an efficient approach to acces...

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