Construction of multiferrocenes end-capped metallodendrimers via coordination-driven self-assembly and their electrochemical behavior

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成果类型：

期刊论文

作者：

Wang, Lilei;Chen, Li-Jun;Ma, Jian-Qiu;Wang, Cui-Hong;Tan, Hongwei;...

通讯作者：

Xu, Lin

作者机构：

[Wang, Cui-Hong; Chen, Li-Jun; Wang, Lilei; Xu, Lin] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 N Zhongshan Rd, Shanghai 200062, Peoples R China.

[Tan, Hongwei; Ma, Jian-Qiu] Beijing Normal Univ, Dept Chem, Beijing 100050, Peoples R China.

[Huang, Junhai] China State Inst Pharmaceut Ind, Zhangheng Inst, 1599 Zhangheng Rd, Shanghai, Peoples R China.

[Xiao, Fengping] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.

通讯机构：

[Xu, Lin] E

East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663 N Zhongshan Rd, Shanghai 200062, Peoples R China.

语种：

英文

关键词：

Electronic properties;Electrospray ionization;Mass spectrometry;Metals;Molecular orbitals;Orbital calculations;Coordination-driven self assembly;Electrochemical;Electrochemical behaviors;Electrochemical studies;Ionization time of flight mass spectrometries;Metallodendrimer;Multiferrocene;Semi-empirical molecular orbital method;Self assembly

期刊：

Journal of Organometallic Chemistry

ISSN：

0022-328X

年：

2016

卷：

823

页码：

1-7

DOI：

10.1016/j.jorganchem.2016.09.001

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21302058, 21672070]; Research Fund for the Doctoral Program of Higher Education of ChinaResearch Fund for the Doctoral Program of Higher Education of China (RFDP)Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP) [20130076120006]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities; Shanghai Key Laboratory of Chemical Biology; Self-determined Research Funds of Central China Normal University from the Colleges' Basic Research and Operation of Ministry of Education, China [CCNU14A05013]

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本校为其他机构

院系归属：

化学学院

摘要：

The construction of a new family of multiferrocenes end-capped metallodendrimers H1–4 with various generations via coordination-driven self-assembly was described. The structures of these metallodendrimers H1–4 were characterized by multinuclear NMR {1H and31P} spectroscopy, electrospray ionization time-of-flight mass spectrometry (ESI-TOF-MS), and the PM6 semiempirical molecular orbital method. Insight into the structure and electronic properties of these supramolecules was obtained through electrochem...

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Construction of multiferrocenes end-capped metallodendrimers via coordination-driven self-assembly and their electrochemical behavior

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