We are grateful to the National Natural Science Foundation of China (No. 21232003, 21202053, 21472058 and 21572074) and Outstanding Youth Funding in Hubei Province (2015CFA033) for support of this research. A.B. is thankful to the China Scholarship Council for doctoral stipends.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A catalytic asymmetric allylic alkylation reaction of 3-aryloxindoles was accomplished via a dual catalysis merging palladium catalysis and asymmetric H-bonding catalysis for the first time. Using this approach, allylated oxindoles bearing chiral all-carbon quaternary centers were produced in high yields with good enantioselectivities (up to 92 % yield and 96:4 er). (Figure presented.). ...