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OMEGA-HYDRO-PERFLUOROALKYL PYRIMIDINYL NITROXIDES

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成果类型:
期刊论文
作者:
ZHAO, CX*;ZHOU, ZB;HE, HY;WENG, ZY;XUE, SJ;...
通讯作者:
ZHAO, CX
作者机构:
[ZHANG, AD; WENG, ZY; XUE, SJ; ZHAO, CX; ZHOU, ZB; HE, HY] CENT CHINA NORMAL UNIV,DEPT CHEM,WUHAN 430070,PEOPLES R CHINA.
[ZHAO, CX] HUAZHONG UNIV SCI & TECHNOL,DEPT CHEM,WUHAN 430074,PEOPLES R CHINA.
通讯机构:
[ZHAO, CX] H
HUAZHONG UNIV SCI & TECHNOL,DEPT CHEM,WUHAN 430074,PEOPLES R CHINA.
语种:
英文
关键词:
Nitroxides;Nitroxyl;Pyrimidinyl;PhNO;Substitute Aniline
期刊:
Research on Chemical Intermediates
ISSN:
0922-6168
年:
1995
卷:
21
期:
1
页码:
1-6
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
Twenty-two polysubstituted 2-aminopyrimidines dissolved in F1 13 (CC1F2-CCl2F) solutions containing ([H(CF2CF2)nCO2]2 n = 1,2) and H(CF2CF2)nNO [↔ H(CF2CF2)n• + NO] have been oxidized into detectable ω-H-perfluoroalkyl pyrimidinyl nitroxides along with neutral products. A mechanism involving Habstraction from the amino groups by H(CF2CF2)nN(O•)(CF2CF2)nH and the subsequent radical steps was suggested for the generation of the nitroxides. Some relationships between aN values and the nature of the ring substituen...

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