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In Situ Polymerized PAN-Assisted S/C Nanosphere with Enhanced High-Power Performance as Cathode for Lithium/Sulfur Batteries

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成果类型:
期刊论文
作者:
Hu, Hao;Cheng, Haoyan;Liu, Zhengfei;Li, Guojian;Zhu, Qianchen;...
通讯作者:
Yu, Ying
作者机构:
[Li, Guojian; Zhu, Qianchen; Hu, Hao; Cheng, Haoyan; Liu, Zhengfei; Yu, Ying] Cent China Normal Univ, Inst Nanosci & Nanotechnol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
通讯机构:
[Yu, Ying] C
Cent China Normal Univ, Inst Nanosci & Nanotechnol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Lithium/sulfur battery;PAN-assisted;vulcanization;high-power;sulfur cathode
期刊:
NANO LETTERS
ISSN:
1530-6984
年:
2015
卷:
15
期:
8
页码:
5116-5123
基金类别:
National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21377044]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2015CFA037]; Wuhan Planning Project of Science and Technology [2014010101010023]; CCNU from the MOE [CCNU15ZD007, CCNU15KFY005]
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
Carbonaceous and polymer materials are extensively employed as conductor and container to encapsulate sulfur particles and limit polysulfide dissolution. Even so, high-power performance is still far from satisfaction due to the expansion and collapse of the electrode materials during thousands of charge-discharge process. Herein, it is found that colloidal carbon sphere with high elastic coefficient can be utilized as a framework to load sulfur, which can trap soluble polysulfides species in the pores within the sphere and efficaciously improve...

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