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Nitrogen-coordinated metallic cobalt disulfide self-encapsulated in graphitic carbon for electrochemical water oxidation

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成果类型:
期刊论文
作者:
Zhang, Wei;Chen, Wenjuan;Xiao, Qin;Yu, Luo;Huang, Chuqiang;...
通讯作者:
Yu, Ying
作者机构:
[Xiao, Qin; Huang, Chuqiang; Zhang, Wei; Chen, Wenjuan; Yu, Ying; Yu, Luo] Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Peoples R China.
[Yu, Luo] Univ Houston, Dept Phys, Houston, TX 77204 USA.
[Yu, Luo] Univ Houston, TcSUH, Houston, TX 77204 USA.
[Lu, Gongxuan] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synthsis & Select Oxidat, Lanzhou 730000, Peoples R China.
[Morawski, A. W.] West Pomeranian Univ Technol, Dept Inorgan Chem Technol & Environm Engn, Ul Pulaskiego 10, PL-70322 Szczecin, Poland.
通讯机构:
[Yu, Ying] C
Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
CoS2;Electrocatalysis;Oxygen evolution reaction;X-ray absorption spectroscopy
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2020
卷:
268
页码:
118449
基金类别:
This work was financially supported by the National Natural Science Foundation of China (Nos. 21573085 and 51872108 ), the Wuhan Planning Project of Science and Technology (No. 2018010401011294 ), self-determined research funds of Central China Normal University (CCNU) from the college’s basic research and operation through the Chinese Ministry of Education (No. CCNU18TS034 ), and the Excellent Doctoral Dissertation Cultivation Grant from CCNU (No. 2018YBZZ086 ). We thank the 1W2B station in the Beijing Synchrotron Radiation Facility (BSRF) for XAS measurement. We thank Prof. M. Qiu for DFT calculations.
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
Oxygen evolution reaction (OER) is a key process in electrochemical conversion technologies. The rational design of efficient catalyst and understanding of structure-property relationship in catalysis still remain grand challenge. Herein, nitrogen-coordinated CoS2 ultrafine nanoparticles (NPs) self-encapsulated in graphene (N-CoS2@graphene) are obtained through employing zeolitic imidazolate frameworks (ZIFs) as precursors. An in-situ N-coordinated and graphene self-encapsulated strategy is developed to improve the catalytic activity and stabil...

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