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Self doping promoted photocatalytic removal of no under visible light with bi2moo6: Indispensable role of superoxide ions

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成果类型:
期刊论文
作者:
Ding, Xing;Ho, Wingkei*;Shang, Jian;Zhang, Lizhi
通讯作者:
Ho, Wingkei
作者机构:
[Ding, Xing; Ho, Wingkei] Hong Kong Inst Educ, Dept Sci & Environm Studies, Hong Kong, Hong Kong, Peoples R China.
[Ding, Xing; Ho, Wingkei] Hong Kong Inst Educ, Ctr Educ Environm Sustainabil, Hong Kong, Hong Kong, Peoples R China.
[Ding, Xing] Huazhong Agr Univ, Coll Sci, Wuhan 430070, Peoples R China.
[Zhang, Lizhi; Shang, Jian] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Inst Environm Chem,Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Ho, Wingkei] H
Hong Kong Inst Educ, Dept Sci & Environm Studies, Hong Kong, Hong Kong, Peoples R China.
语种:
英文
关键词:
Bi2MoO6;NO;Photocatalytic;Self doping;Visible light
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2016
卷:
182
页码:
316-325
基金类别:
This research is mainly financially supported by the research grant of Early Career Scheme (ECS 809813 ) from the Research Grant Council, Hong Kong SAR Government . This work was supported from our collaborators by National Natural Science Funds for Distinguished Young Scholars (Grant 21425728 ), National Basic Research Program of China (973 Program) (Grant 2013CB632402 ), National Science Foundation of China (Grants 21177048 , and 51472100 ), National Natural Science Foundation of China ( 51572101 ), Key Project of Natural Science Foundation of Hubei Province (Grant 2013CFA114 ), Self-Determined Research Funds of CCNU from the Colleges’ Basic Research and Operation of MOE (Grant CCNU14Z01001 ), and Excellent Doctorial Dissertation Cultivation Grant from Central China Normal University (Grant 2013YBYB56 ). We also thank the National Supercomputer Center in Jinan for providing high-performance computation.
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
In this study, we demonstrated that the reactive species generation of Bi2MoO6 under visible light can be regulated by Bi self-doping via a simple soft-chemical method. Density functional theory calculations and systematical characterization results revealed that Bi self-doping could not only promote the separation and transfer of photogenerated electron-hole pairs of Bi2MoO6 but also alter the position of valence and conduction band without changing its preferential crystal orientations, morphology, visible light absorption as well as band gap...

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