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A highly efficient carbon-sulfur bond formation reaction via microwave-assisted nucleophilic substitution of thiols to polychloroalkanes without a transition-metal catalyst

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成果类型:
期刊论文
作者:
Cao, Yi-Ju;Lai, Yuan-Yuan;Cao, Hong;Xing, Xiao-Ning;Wang, Xiang;...
通讯作者:
Xiao, Wen-Jing
作者机构:
[Wang, Xiang; Lai, Yuan-Yuan; Xiao, WJ; Cao, Hong; Cao, Yi-Ju; Xing, Xiao-Ning] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Hubei, Peoples R China.
[Xiao, Wen-Jing] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Xiao, Wen-Jing] C
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
microwave;sulfide;thiol;nucleophilic substitution.
期刊:
CANADIAN JOURNAL OF CHEMISTRY
ISSN:
0008-4042
年:
2006
卷:
84
期:
11
页码:
1529-1533
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
An efficient carbon-sulfur bond formation reaction has been developed under microwave irradiation. This reaction affords a novel and rapid synthesis of thioacetals and sulfides under mild conditions. This method is particularly noteworthy given its experimental simplicity and high generality, and no transition-metal catalysts were need...

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