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Highly Improved Chiral-Selective Resolution in Pillar[5]arene-Functionalized Molecularly Imprinted Membranes

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成果类型:
期刊论文
作者:
Wang, Li;Li, Guang;Yang, Lei;Qu, Haonan;Cheng, Jing;...
通讯作者:
Cheng, Jing(chengjingok@mail.ccnu.edu.cn);Li, Haibing(lhbing@mail.ccnu.edu.cn)
作者机构:
[Wang, Li; Li, Guang; Yang, Lei; Li, Haibing; Cheng, Jing; Qu, Haonan] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol CCNU, Minist Educ, Wuhan 430079, Peoples R China.
[Barakat, Dalia A.; Abdallah, Mohammed] Cairo Univ, Fac Agr, Dept Econ Entomol & Pesticides, Giza 12411, Egypt.
通讯机构:
[Jing Cheng; Haibing Li] K
Key Laboratory of Pesticide and Chemical Biology (CCNU), Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, P. R China
语种:
英文
关键词:
chiral separation;membrane separation;molecularly imprinted polymer;pillar[5]arenes;S/R-triadimefon
期刊:
ACS APPLIED POLYMER MATERIALS
ISSN:
2637-6105
年:
2022
卷:
4
期:
9
页码:
6723-6730
基金类别:
This work was financially supported by the National Natural Science Foundation of China (21677058 and 21772055), the 111 Project (B17019), and Self-determined research funds of CCNU from the colleges’ basic research and operation of MOE.
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
It is a challenging task to achieve the effective separation of chiral compounds under simple and rapid conditions. In order to solve this problem, this study used the molecularly imprinted membrane (MIM) technology developed on the basis of biological semi-permeable membranes, using S-triadimefon as the template molecule, and successfully prepared MIMs by photo-initiated polymerization. By adding macrocyclic molecular 1,4-bis(allyloxy)pillar[5]arene as a functional monomers, the effectiveness of the chiral recognition sites of the target molec...

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