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Fabrication of ultrafine metastable Ru-B alloy for catalytic hydrogenation of NEC at room temperature

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成果类型:
期刊论文
作者:
Pei, Qijun;Yu, Jiafeng;Qiu, Guanghao;Tan, Khai Chen;Wen, Junfeng;...
通讯作者:
Li Rao
作者机构:
[Pei, Qijun; Yu, Jiafeng; Qiu, Guanghao; Yu, Yang; Guo, Jianping] Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
[Wen, Junfeng] School of Chemistry and Chemical Engineering, Yulin University, Yulin 719000, China
[Rao, Li] Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
通讯机构:
[Li Rao] H
Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China
语种:
英文
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2023
卷:
336
页码:
122947
基金类别:
CRediT authorship contribution statement Qijun Pei: Investigation, Methodology, acquisition, Writing – original draft. Jiafeng Yu: Formal analysis, Writing - Review & Editing. Guanghao Qiu: Investigation, Methodology. Khai Chen Tan: Formal analysis, Methodology. Junfeng Wen: Formal analysis, Methodology. Yang Yu: Formal analysis, Methodology. Jintao Wang: Formal analysis, Methodology. Jiaquan Guo: Formal analysis, Methodology. Jianping Guo: Formal analysis, Methodology. Li Rao: Investigation, Writing - Review & Editing. Teng He
机构署名:
本校为通讯机构
院系归属:
化学学院
摘要:
Liquid organic hydrogen carriers (LOCHs) hold considerable potential for large-scale and long-distance energy/hydrogen storage and transportation. However, due to the lack of efficient catalysts, harsh conditions are needed for the reversible hydrogen uptake and/or release of LOHCs. Herein, a one-pot method was developed to synthesize an ultrafine metastable Ru-B alloy, where the geometrical and electronic structure of Ru is well modulated by B. To our delight, the hydrogenation of N-ethylcarbazole (NEC, one of the promising LOHC candidates) could be catalyzed by Ru-B alloy with ca. 99 % yield...

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