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Selective Adsorption and Steric Recognition by Molecularly Imprinted Polymers: a Study on Molecular Self-Assembly and its Effect on Selectivity

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成果类型:
期刊论文
作者:
Zhang, Daonian;Li, Songjun*;Huang, Jun;Luo, Gang
通讯作者:
Li, Songjun
作者机构:
[Li, Songjun; Zhang, Daonian; Huang, Jun; Luo, Gang] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Li, Songjun] C
Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Adsorption;Molecularly imprinting polymer;Self-assembly;Steric selectivity
期刊:
High Performance Polymers
ISSN:
0954-0083
年:
2006
卷:
18
期:
6
页码:
949-960
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This article presents an interesting study on molecular self-assembly and its effect on steric recognition by molecularly imprinted polymers. With S-naproxen as the template and acrylamide as the functional monomer, the self-assembly appears to play important roles in the selective adsorption, affecting not only the adsorption amount but also the enantioselective recognition. Both of them become evident by the change of monomer-template ratio. An increase in the monomer-template ratio will result in a higher level of adsorption. The best select...

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