In this paper we prove that for any prime power q equivalent to 3 (mod 8) there exist 4 - {q(2); k, k, k, k; lambda} supplementary difference sets (SDSs) with k = q(q - 1)/2, lambda 4k - q(2), and Hadamard matrices of order 4q(2), and give several constructions of these SDSs. Moreover, combining the results of reference [1], we conclude that for any prime p equivalent to 3 (mod 8) and integer r greater than or equal to ...