期刊论文

Guo, Yanbing

英文

ACS Applied Materials & Interfaces

1944-8244

2018

10

20

17167-17174

10.1021/acsami.8b02367

The authors are grateful for the financial support from the Recruitment Program of Global Young Experts start-up funds, The Program of Introducing Talents of Discipline to Universities of China (111 program, B17019), and the National Natural Science Foundation of China (21777051).

本校为第一且通讯机构

The activation of molecular oxygen (O2) is extremely crucial in heterogeneous oxidations for various industrial applications. Here, a charge-transfer complex CuTCNQ nanowire (CuTCNQ NW) array grown on the copper foam was first reported to show CO catalytic oxidation activity at a temperature below 200 °C with the activated O2 as an oxidant. The molecular O2 was energetically activated over the Cu(I)-mediated C=N bond with a lower energy of -1.167 eV and preferentially reduced to •O2- through one-electron transfer during the activation process...