NNSFCNational Natural Science Foundation of China [21971081, 21622201, 91856119, 21820102003, 21772053]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]
机构署名：
本校为第一且通讯机构
院系归属：
化学学院
摘要：
Catalytic enantioselective chemical reactions involving highly reactive radical species remain largely unexplored. We report herein for the first time a novel enantioselective radical ring-opening cyanation of redox-active oxime esters by dual photoreodox and copper catalysis. This mild protocol shows good functional group tolerance and broad substrate scope, producing a wide range of optically active alkyl dinitriles with high yields and excellent enanti...
