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Electroreductively Induced Radicals for Organic Synthesis

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成果类型:
期刊论文
作者:
Xiang, Huaming;He, Jinyu;Qian, Weifeng;Qiu, Mingqiang;Xu, Hao;...
通讯作者:
Cuiju Zhu<&wdkj&>Mingqiang Qiu
作者机构:
[Xu, Hao; Wang, Yanzhao; Ouyang, Yanyan; Duan, Wenxi; Xiang, Huaming; Qian, Weifeng; Zhu, Cuiju; He, Jinyu; Qiu, Mingqiang] Cent China Normal Univ, Coll Chem, Key Lab Pesticides & Chem Biol, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
通讯机构:
[Cuiju Zhu; Mingqiang Qiu] A
Authors to whom correspondence should be addressed.<&wdkj&>Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, China
语种:
英文
关键词:
electroreduction;radical chemistry;electrochemical synthesis;cathodic reduction
期刊:
Molecules
ISSN:
1420-3049
年:
2023
卷:
28
期:
2
页码:
857-
基金类别:
Conceptualization, C.Z. and H.X. (Huaming Xiang); validation, C.Z., H.X. (Hao Xu) and M.Q.; writing—original draft preparation, C.Z.; writing—review and editing, C.Z., H.X. (Huaming Xiang), J.H., W.Q., H.X. (Hao Xu), W.D., Y.O., Y.W.; visualization, C.Z.; supervision, C.Z.; project administration, C.Z.; funding acquisition, C.Z. All authors have read and agreed to the published version of the manuscript. This research was funded by the National Natural Science Foundation of China and grant number was 22201089.
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
Organic electrochemistry has attracted tremendous interest within the novel sustainable methodologies that have not only reduced the undesired byproducts, but also utilized cleaner and renewable energy sources. Particularly, oxidative electrochemistry has gained major attention. On the contrary, reductive electrolysis remains an underexplored research direction. In this context, we discuss advances in transition-metal-free cathodically generated radicals for selective organic transformations since 2016. We highlight the electroreductive reaction of alkyl radicals, aryl radicals, acyl radicals,...

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