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Hematite facet confined ferrous ions as high efficient Fenton catalysts to degrade organic contaminants by lowering H2O2decomposition energetic span

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成果类型:
期刊论文
作者:
Huang, Xiaopeng;Hou, Xiaojing;Zhao, Jincai;Zhang, Lizhi*
通讯作者:
Zhang, Lizhi
作者机构:
[Zhang, Lizhi; Hou, Xiaojing; Huang, Xiaopeng; Zhao, Jincai] Cent China Normal Univ, Coll Chem, Inst Environm Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Zhang, Lizhi] C
Cent China Normal Univ, Coll Chem, Inst Environm Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Confined ferrous ions;Energetic span;Fenton oxidation;Hematite architectures;Structure-dependent reactivity
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2016
卷:
181
页码:
127-137
基金类别:
National Natural Science Funds for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21173093, 21177048, 21477044]; Key Project of Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; Self-Determined Research Funds of CCNU from the Colleges' Basic Research and Operation of MOE [CCNU14Z01001, CCNU14KFY002]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, we demonstrate that ferrous ions confined on the hematite facets can significantly promote the H2O2 decomposition to produce •OH for more efficient organic contaminants degradation than the unconfined counterparts, while hematite nanorods with exposed {001} and {110} facets exhibit better confining effect than nanoplates with exposed {001} facets. Experimental results revealed that the H2O2 decomposition efficiency of hematite facet confined ferrous ions was affected by the amount of surface confined ferrous ions, and also gover...

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