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CH4 combustion over a commercial Pd/CeO2-ZrO2 three-way catalyst: Impact of thermal aging and sulfur exposure

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成果类型:
期刊论文
作者:
Yang, Weiwei;Kim, Mi-Young;Polo-Garzon, Felipe;Gong, Jian;Jiang, Xiao;...
通讯作者:
Wang, Xiang(xiangwang.chn@gmail.com)
作者机构:
[Jiang, Xiao; Wang, Xiang; Yu, Xinbin; Yang, Weiwei; Polo-Garzon, Felipe; Huang, Zhennan; Chi, Miaofang] Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA.
[Yang, Weiwei; Guo, Yanbing; Wu, Zili] Cent China Normal Univ, Inst Environm & Appl Chem, Coll Chem, Key Lab Pesticide & Chem Biol,Minist Educ, Wuhan 430079, Peoples R China.
[Kim, Mi-Young; Gong, Jian] Cummins Inc, Corp Res & Technol, 1900 McKinley Ave, Columbus, IN 47201 USA.
通讯机构:
[Xiang Wang; Zili Wu] C
Chemical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, United States
语种:
英文
关键词:
CH4 oxidation;Commercial Pd/CeO2-ZrO2;Sulfur poisoning;Thermal aging;Three-Way Catalyst
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2023
卷:
451
页码:
138930
基金类别:
This research is sponsored by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division, Catalysis Science program. Some of the work including IR, electron microscopy, Raman and TPR was conducted as part of a user project at the Center for Nanophase Materials Sciences (CNMS), which is a US Department of Energy, Office of Science User Facility at Oak Ridge National Laboratory. WY acknowledges the fellowship from China Scholarship Council.
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
Thermal aging and sulfur poisoning are major problems influencing the efficiency and lifetime of natural gas three-way catalysts (TWCs) during real-world operation. In the present study, thermal aging and sulfur-induced deactivations on CH4 combustion were investigated over commercial monolithic honeycombs, i.e., Pd/CexZr1-xO2 (CZ)-based TWCs that are thermally aged in the bench (HTA), followed by being operated behind the stoichiometric natural gas engine in high sulfur fuel (HTA + S). Both HTA and HTA + S samples show degraded performance in ...

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