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In-situ polymerization of dual monomers for constructing a highly elastic PAA-co-PAM network enables efficient and stable Carbon-based perovskite solar cells

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成果类型:
期刊论文
作者:
Ran, Hongbing;Qu, Qiyu;Wang, Shiyu;Zhao, Yue;Wang, Yulin;...
通讯作者:
Tang, YW
作者机构:
[Zhao, Yue; Tang, Yiwen; Ran, Hongbing; Wang, Shiyu; Chen, Xiangjie; Wang, Yulin; Qu, Qiyu; Tang, YW] Cent China Normal Univ, Inst Nanosci & Technol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
通讯机构:
[Tang, YW ] C
Cent China Normal Univ, Inst Nanosci & Technol, Coll Phys Sci & Technol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Perovskite solar cells;Carbon-Based;In-situ polymerization;Dual Monomer;Stabilty;Passivating defects
期刊:
Chemical Engineering Journal
ISSN:
1385-8947
年:
2024
卷:
498
页码:
155100
基金类别:
National Natural Science Foundation of China [51972133, 51572102]
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
During the preparation of carbon-based perovskite solar cells, the external stress applied to the carbon paste inevitably compresses the perovskite lattice, potentially damaging its structure and generating defects. This poses a significant threat to the efficiency and stability of devices. Herein, a dual monomer irregular in-situ polymerization method was developed to form a highly elastic network (acrylamide-co-acrylic acid, PAA-co-PAM) within perovskite films, serving as both a ligament to passivate defects and a buffer to improve film stability under stress. The results demonstrated that m...

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