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Enantioselective Separation of Agricultural Fungicides Based on Chiral Hybrid Nanochannel Membranes

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成果类型:
期刊论文
作者:
Xu, Weiwei;Li, Guang;Qu, Haonan;Zhang, Haifan;Ma, Cuiguang;...
通讯作者:
Cheng, Jing;Li, HB
作者机构:
[Cheng, Jing; Li, Guang; Xu, Weiwei; Li, Haibing; Ma, Cuiguang; Li, HB; He, Qiang; Zhang, Haifan; Qu, Haonan] Cent China Normal Univ, Coll Chem, Natl Key Lab Green Pesticide, Wuhan 430079, Peoples R China.
通讯机构:
[Cheng, J; Li, HB ] C
Cent China Normal Univ, Coll Chem, Natl Key Lab Green Pesticide, Wuhan 430079, Peoples R China.
语种:
英文
期刊:
CHEMISTRY OF MATERIALS
ISSN:
0897-4756
年:
2024
卷:
36
期:
4
页码:
1975-1981
基金类别:
National Key Research and Development Program [2023YFF0717100, 2021YFA0716702]; National Key Research and Development Program [22371086, 22071074]; National Natural Science Foundation of China; CCNU
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Chiral fungicides have been widely used for disease control in agricultural cultivation due to their advantages of high efficiency, low toxicity, high selectivity, and low residue. However, the enantiomers of chiral fungicides in the chiral environment often exhibit different physiological and biochemical properties and sometimes even diametrically opposite effects. This work modified the chiral alanine-functionalized pillar[5]arene within PET nanochannels. The binary hybridized nanochannel exhibits high selectivity for the chiral fungicide Propranolol, with a selectivity coefficient of 7.36, ...

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