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Insight into core-shell dependent anoxic Cr(VI) removal with Fe@Fe2O3 nanowires: Indispensable role of surface bound Fe(II)

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成果类型:
期刊论文
作者:
Mu, Yi;Ai, Zhihui*;Zhang, Lizhi;Song, Fahui
通讯作者:
Ai, Zhihui
作者机构:
[Zhang, Lizhi; Mu, Yi; Ai, Zhihui; Song, Fahui] Cent China Normal Univ, Inst Environm Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Ai, Zhihui] C
Cent China Normal Univ, Inst Environm Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Cr(VI) removal;adsorption;anoxic;core-shell [email protected]2O3 nanowires;surface bound Fe(II)
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2015
卷:
7
期:
3
页码:
1997-2005
基金类别:
National Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21173093, 21177048, 21477044, 21273088]; National Science Fund for Distinguished Young ScholarsNational Natural Science Foundation of China (NSFC)National Science Fund for Distinguished Young Scholars [21425728]; Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2013CFA114]; CCNU from the Colleges' Basic Research and Operation of MOEMinistry of Education, Singapore [CCNU14Z01001, CCNU14KFY002]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
In this study, we investigated the anoxic Cr(VI) removal with core-shell Fe@Fe2O3 nanowires. It was found the surface area normalized Cr(VI) removal rate constants of Fe@Fe2O3 nanowires first increased with increasing the iron oxide shell thickness and then decreased, suggesting that Fe@Fe2O3 nanowires possessed an interesting core-shell structure dependent Cr(VI) removal property. Meanwhile, the Cr(VI) removal efficiency was positively correlated to the amount of surface bound Fe(II). This result revealed that the core-shell structure dependen...

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