期刊论文

Chen, Jia-Rong;Xiao, Wen-Jing

英文

CHEMISTRY-A EUROPEAN JOURNAL

0947-6539

2018

24

63

16895-16901

10.1002/chem.201804229

We are grateful to the NNSFC (21472057, 21472058, 21622201 and 21772053), the Science and Technology Department of Hubei Province (2016CFA050 and 2017AHB047), and the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019) for support of this research. We offer special thanks to Profs. Axel Jacobi von Wangelin and Burkhard Kçnig for valuable discussions and suggestions.

本校为第一且通讯机构

A new synergistic multicatalytic activation mode of eosin Y has been discovered by exploiting the redox potential of its ground state and excited state. This catalytic strategy proves to be an enabling tool for visible-light-driven sequential benzylic C−H amination and oxidation of o-benzyl-N-methoxyl-benzamides when using Selectfluor as a hydrogen atom transfer (HAT) reagent and O2 as oxidant. Efficient synthesis of a range of diversely functionalized 3-hydroxyisoindolinones can thus be achieved with good yields and selectivity at mild reacti...