期刊论文

Chen, Jia-Rong;Xiao, Wen-Jing

英文

CHEMISTRY-A EUROPEAN JOURNAL

0947-6539

2019

25

34

8024-8029

10.1002/chem.201901665

We are grateful to the NNSFC (91856119, 21622201, 21820102003, and 21772053), the Science and Technology Department of Hubei Province (2016CFA050 and 2017AHB047), and the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019) for their support to this research.

本校为第一且通讯机构

Alkene bifunctionalizations are powerful tools for the rapid construction of structurally complex and valuable scaffolds, and such reactions typically involve the use of transition-metal catalysts or organocatalysts. Here, we report for the first time a photogenerated neutral nitrogen radical catalyzed intermolecular alkene bifunctionalization by using allyl sulfones as the source of both the carbon and the sulfone functionalities under mild conditions. The key to the success of this protocol involves the visible-light-mediated photocatalytic i...