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The effect of ZnO coating on LiMn2O4 cycle life in high temperature for lithium secondary batteries

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成果类型:
期刊论文
作者:
Liu, Hoawen*;Cheng, Cuixia;Zongqiuhu;Zhang, Keli
通讯作者:
Liu, Hoawen
作者机构:
[Liu, Hoawen] S Cent Univ Nationalities, Coll Chem & Mat Sci, Key Lab Catalysis & Mat Sci Hubei Privence, Wuhan 430074, Peoples R China.
Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China.
通讯机构:
[Liu, Hoawen] S
S Cent Univ Nationalities, Coll Chem & Mat Sci, Key Lab Catalysis & Mat Sci Hubei Privence, Wuhan 430074, Peoples R China.
语种:
英文
关键词:
Coating;Improvement;Lithium ion battery;Spinel;Surface
期刊:
Materials Chemistry and Physics
ISSN:
0254-0584
年:
2007
卷:
101
期:
2-3
页码:
276-279
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
The surface of the spinel LiMn2O4 was modified with zinc oxide by a chemical process to improve its electrochemical performance at high temperatures. The physical properties of the prepared products have been investigated by thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-rays analysis (EDAX). The charge/discharge of the materials was carried at 1 mA/cm2 in the range of 3.0 and 4.4 V at 55 °C. The discharge capacity of ZnO-coated LiMn2O4 (117 mAh/g) showed only 3% loss of the initial capacity (121 mAh/g) over 60 cycles. The cycle a...

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