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Rationally designing molecularly imprinted polymer toward a high specific adsorbent by using metal as assembled pivot

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成果类型:
期刊论文
作者:
Zheng, Ming-Xia;Li, Song-Jun*;Luo, Xuan
通讯作者:
Li, Song-Jun
作者机构:
[Li, Song-Jun; Luo, Xuan; Zheng, Ming-Xia] Cent China Normal Univ, Minist Educ, Coll Chem, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Li, Song-Jun] C
Cent China Normal Univ, Minist Educ, Coll Chem, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
molecularly imprinted polymer;adsorption;metal;assembled pivot
期刊:
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
ISSN:
1060-1325
年:
2007
卷:
44
期:
11
页码:
1187-1194
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This article presents an original work aimed at rationally designing molecularly imprinted polymer (MIP) toward a high specific adsorbent. Assembling with cobalt as the pivot, the MIP was prepared by coordinating polymerizable monomers around an inducible template. The use of pivot obviously plays a positive role on increasing the specificity of MIP, so as to adsorb more for the template and less for its analogue. Related studies indicate that these may be a result of increasing specific interaction, which makes the MIP capable of recognizing the imprint species. Further information from therm...

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