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Rationally designing molecularly imprinted polymer towards predetermined high selectivity by using metal as assembled pivot

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成果类型:
期刊论文
作者:
Li, Songjun*;Liao, Cong;Li, Wuke;Chen, Yifeng;Hao, Xiao
通讯作者:
Li, Songjun
作者机构:
[Li, Songjun; Liao, Cong; Hao, Xiao; Li, Wuke; Chen, Yifeng] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Li, Songjun] C
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol Minist Educ, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
adsorption;assembled pivot;metal;molecularly imprinted polymer;selectivity
期刊:
Macromolecular Bioscience
ISSN:
1616-5187
年:
2007
卷:
7
期:
9-10
页码:
1112-1120
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
This article presents an original work aiming at rationally designing a molecularly imprinted polymer (MIP) towards high selective recognition. Assembled with (S)-naproxen as a template and 4-vinylpyridine as a functional monomer, a certain amount of cobalt, as pivot, is added for the preparation of MIP. The result indicates that the use of pivot plays obviously a positive role in increasing the specificity of MIP, so as to adsorb more for the template and less for its enantiomer. Related information indicates that this, in logic, can be a result of increasing match between binding sites and t...

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