Motivated by the possible large direct CP asymmetry of B¯d0→D+D− decays measured by the Belle Collaboration, we investigate double charm Bu,d and Bs decays in the minimal supersymmetric standard model with R-parity violation. We derive the bounds on relevant R-parity violating couplings from the current experimental data, which show quite consistent measurements among relative collaborations. Using the constrained parameter spaces, we explore R-parity violating effects on other observables in these decays, which have not been measured or hav...