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A controllable reduction-oxidation coupling process for chloronitrobenzenes remediation: From lab to field trial

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成果类型:
期刊论文
作者:
Wei, Kai;Wan, Yanyan;Liao, Minzi;Cao, Shiyu;Zhang, Hao;...
通讯作者:
Ai, Z.;Zhang, L.
作者机构:
[Wei, Kai; Wan, Yanyan; Zhang, Lizhi; Zhang, Hao; Ai, Zhihui; Gu, Huayu; Ling, Cancan; Liao, Minzi; Cao, Shiyu; Gong, Jingming; Peng, Xing; Li, Meiqi] Cent China Normal Univ, Inst Environm & Appl Chem, Key Lab Pesticide & Chem Biol, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Peoples R China.
[Zhang, Lizhi; Shi, Yanbiao] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China.
通讯机构:
[Zhihui Ai] K
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, Institute of Environmental and Applied Chemistry, Central China Normal University, 152 Luoyu Road, Wuhan 430079, PR China
语种:
英文
关键词:
Chloronitrobenzenes;Environmental remediation;H(2)O(2);Reduction-oxidation coupling;Zero-valent iron
期刊:
Water Research
ISSN:
0043-1354
年:
2022
卷:
218
页码:
118453
基金类别:
This work was financially supported by the National Key Research and Development Program of China (Grant 2018YFC1800701, 2018YFC1802003 and 2019YFC1806203), the National Natural Science Foundation of China (Grant U20A20129, 21876058, 21936003). We thank Dr. Jinzhong Wan and Dr. Shaopo Deng in Nanjing Institute of Environmental Science of the Ministry of Ecology and Environment for providing guidance on contaminated field selection and field trial implementation.
机构署名:
本校为第一机构
院系归属:
化学学院
摘要:
Chloronitrobenzenes (CNBs) are typical refractory aromatic pollutants. The reduction products of CNBs often possess higher toxicity, and the electron-withdrawing substituent groups are detrimental to the ring-opening during the oxidation treatment, leading to ineffective removal of CNBs by either reduction or oxidation technology. Herein we demonstrate a controllable reduction-oxidation coupling (ROC) process composed of zero-valent iron (ZVI) and H(2)O(2) for the effective removal of CNBs from both water and soil. In water, ZVI first reduced p...

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