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Salicylic acid complexed with TiO2 for visible light-driven selective oxidation of amines into imines with air

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成果类型:
期刊论文
作者:
Li, Xia;Xu, Hui;Shi, Ji-Long;Hao, Huimin;Yuan, Hong;...
通讯作者:
Lang, Xianjun
作者机构:
[Shi, Ji-Long; Lang, Xianjun; Xu, Hui; Hao, Huimin; Li, Xia] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China.
[Yuan, Hong] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Lang, Xianjun] W
Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China.
语种:
英文
关键词:
Amines;Photocatalysis;Salicylic acid;Surface complex;Titanium dioxide
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2019
卷:
244
页码:
758-766
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21503086, 21773173]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [2042018kf0212]; Wuhan University
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
The interplay of salicylic acid (SA) and reactive oxygen species (ROS) can modulate biotic and abiotic stress of plants, essential biological aerobic oxidation processes. Meanwhile, ROS plays a critical role in TiO2 photocatalytic system for the degradation of organic species. Herein, we developed a system consisted of SA and TiO2 aiming at the selective oxidation of organic molecules by ROS. Interestingly, SA complexed with TiO2 leads to ligand-to-metal charge transfer (LMCT) under visible light irradiation. The charge transfer from ligand (ch...

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