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Electrospun core-shell nanofibers as an adsorbent for on-line micro-solid phase extraction of monohydroxy derivatives of polycyclic aromatic hydrocarbons from human urine, and their quantitation by LC-MS.

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成果类型:
期刊论文
作者:
Chen, Dan;Xu, Hui*
通讯作者:
Xu, Hui
作者机构:
[Chen, Dan; Xu, Hui] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
通讯机构:
[Xu, Hui] C
Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Electrospun nanofiber;Liquid chromatography-mass spectrometry;Monohydroxy polycyclic aromatic hydrocarbons;Online micro-solid phase extraction;Polydopamine;Polystyrene;Silica;Urine
期刊:
Microchimica Acta
ISSN:
0026-3672
年:
2020
卷:
187
期:
1
页码:
57
基金类别:
This research was financially supported by National Natural Science Foundation of China (No. 21675058), Hubei Province Natural Science Fund Project outstanding youth project (No. 2017CFA075), the Fundamental Research Funds for the Central Universities (No. CCNU18TS006), International Joint Research Center for Intelligent Biosensing Technology and Health and the 111 Project B17019. This research was financially supported by National Natural Science Foundation of China (No. 21675058), Hubei Province Natural Science Fund Project outstanding youth project (No. 2017CFA075), the Fundamental Research Funds for the Central Universities (No. CCNU18TS006), International Joint Research Center for Intelligent Biosensing Technology and Health and the 111 Project B17019.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A method is described for automatted on-line micro-solid phase extraction using polydopamine-modified polystyrene/silica electrospun nanofibers as an adsorbent for monohydroxy metabolites of polycyclic aromatic hydrocarbons (OH-PAHs). They were then quantified by liquid chromatography-mass spectrometry. The sorbent has a network structure, high porosity, stability, hydrophilicity and good extraction capacity. Under optimal experimental conditions, the method has (a) wide linear ranges (0.03-25 ng.mL(-1) for 3-hydroxyphenanthrene and 1-hydroxypyrene; and 0.05-25 ng.mL(-1) for 2-naphthol), (b) g...

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