Sixteen N-(O, O-dialkylthiophosphoryl)N'-(4-Chlorobenzoyl) ureas (1a~h) and N- (O, O-dialkylphosphoryl)-N'- (4-Chlorobenzoyl) ureas (2a~h) were synthesized by nucleo- philic addition of (thio)phosphoramide to 4-chlorobenzoyl isocyanate. The structure of all the title compounds were characterized by elemenal analyses, IR, 1~H NMR (31)~p NMR. The ...