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Interfacial engineering enables surface lattice oxygen activation of SmMn2O5 for catalytic propane combustion

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成果类型:
期刊论文
作者:
Liu, Yi;Hu, Haolu;Zheng, Jiamin;Xie, Fei;Gu, Huayu;...
通讯作者:
Pan, Fangfang;Liu, X;Rostamnia, S
作者机构:
[Zheng, Jiamin; Gu, Huayu; Zhang, Lizhi; Hu, Haolu; Liu, Yi; Xie, Fei; Pan, Fangfang; Liu, Xiao] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
[Zhang, Lizhi] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, Shanghai 200240, Peoples R China.
[Rostamnia, Sadegh] Iran Univ Sci & Technol, Dept Chem, Organ & Nano Grp, Tehran 1684613114, Iran.
通讯机构:
[Pan, FF; Liu, X ] C
[Rostamnia, S ] I
Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
Iran Univ Sci & Technol, Dept Chem, Organ & Nano Grp, Tehran 1684613114, Iran.
语种:
英文
关键词:
Mullite SmMn2O5;Lattice oxygen activation;Propane oxidation;Interface regulation;Electron transfer
期刊:
Applied Catalysis B: Environmental
ISSN:
0926-3373
年:
2023
卷:
330
页码:
122649
基金类别:
CRediT authorship contribution statement All persons who have made substantial contributions to the work reported in the manuscript approved the final version. Yi Liu: Conceptualization, Methodology, Investigation, Writing – original draft. Haolu Hu: Validation, Methodology, Investigation. Jiamin Zheng: Visualization. Fei Xie: Validation. Huayu Gu: Visualization. Sadegh Rostamnia: Writing – review & editing. Fangfang Pan: Writing – review & editing. Xiao Liu: Writing, Supervision, acquisition – review & editing. Lizhi Zhang:
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Surface lattice oxygen (Olatt) over transition metal oxides plays a pivotal role in catalytic combustion of automobile exhaust. The insufficient Olatt activity at low temperatures, however, remains the key problem restricting its practical application. To overcome this deficiency, we activated the Olatt of mullite SmMn2O5 through the interface fabrication with spinel Co3O4. The optimized Co3O4/SmMn2O5 catalyst exhibited 90% conversion at 247 °C for the typical automobile exhaust propane combustion, 77 °C lower than the original SmMn2O5. Addit...

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