期刊论文

Chen, Jia-Rong

英文

Organic Letters

1523-7060

2017

19

13

3620-3623

10.1021/acs.orglett.7b01609

NNSFCNational Natural Science Foundation of China (NSFC) [21472058, 21472057, 21622201, 21232003]; Distinguished Youth Foundation of Hubei Province [2016CFA050]; CCNU [CCNU17TS0011, CCNU16JCZX02]; Program of Introducing Talents of Discipline to Universities of China (111 Program) [B17019]

本校为第一且通讯机构

A novel photocatalytic hydrazonyl radical-mediated radical cyclization/allylation cascade reaction of beta,gamma-unsaturated hydrazones is developed using allyl sulfones and Morita-Baylis-Hillman adduct as allyl sources, which provides an efficient and practical access to various diversely functionalized dihydropyrazoles and tetrahydropyridazines. The reaction is enabled by controllable generation of hydrazonyl radicals via an oxidative deprotonation electron transfer strategy and selective trapping of the re...