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The hydrolysis of ammonia borane catalyzed by NiCoP/OPC-300 nanocatalysts: High selectivity and efficiency, and mechanism

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成果类型:
期刊论文
作者:
Qu, Xiaopeng;Jiang, Rui;Li, Qian;Zeng, Fanan;Zheng, Xue;...
通讯作者:
Xu, Zhimou
作者机构:
[Li, Qian; Qu, Xiaopeng; Zheng, Xue; Xu, Zhimou; Jiang, Rui; Zeng, Fanan] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Sch Opt & Elect Informat, Wuhan 430074, Hubei, Peoples R China.
[Chen, Cunhua] Cent China Normal Univ, Dept Chem, Wuhan 430079, Hubei, Peoples R China.
[Peng, Jing] Wuhan Univ Sci & Technol, Coll Sci, Wuhan 430081, Hubei, Peoples R China.
通讯机构:
[Xu, Zhimou] H
Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Sch Opt & Elect Informat, Wuhan 430074, Hubei, Peoples R China.
语种:
英文
期刊:
Green Chemistry
ISSN:
1463-9262
年:
2019
卷:
21
期:
4
页码:
850-860
基金类别:
National High-tech R&D Program (863 Program) of ChinaNational High Technology Research and Development Program of China [2015AA043302]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [61474048]
机构署名:
本校为其他机构
院系归属:
化学学院
摘要:
The development of highly efficient and cheap catalysts for the release of hydrogen from chemical hydrogen-storage materials is indispensable for the coming clean energy economy. ZIF-67 is transferred into oxygen-doped porous carbon (OPC-300) using two-step heat treatment for the first time. The OPC-300 nanomaterial appears much more effective than other supports, including ZIF-67, graphene oxide and MOF-74, for Ni 0.66 Co 0.19 P 0.15 nanoparticles. NiCoP/OPC-300 nanocatalysts, obtained for the first time, have been successfully synthesized via...

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