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Photochemical behavior of ferrihydrite-oxalate system: Interfacial reaction mechanism and charge transfer process

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成果类型:
期刊论文
作者:
Xu, Tianyuan;Zhu, Runliang;Shang, Huan;Xia, Yabei;Liu, Xiao*;...
通讯作者:
Liu, Xiao
作者机构:
[Zhang, Lizhi; Shang, Huan; Xia, Yabei; Liu, Xiao; Xu, Tianyuan] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Inst Environm & Appl Chem, Minist Educ,Coll Chem, Wuhan 430079, Hubei, Peoples R China.
[Zhu, Runliang] Chinese Acad Sci, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou Inst Geochem, 511 Kehua St, Guangzhou 510640, Guangdong, Peoples R China.
通讯机构:
[Liu, Xiao] C
Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Inst Environm & Appl Chem, Minist Educ,Coll Chem, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
Fe(III)-Ox complex;Ferrihydrite;In-situ ATR-FTIR;Oxalic acid;Reactive oxygen species
期刊:
Water Research
ISSN:
0043-1354
年:
2019
卷:
159
页码:
10-19
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21806050]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2017M622484]; Science and Technology Planning Project of Guangdong Province, China [2017B030314175]; self-determined research funds of CCNU from the colleges' basic research and operation of MOE [20205170462]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Heterogeneous photochemical reactions associated with natural iron (hydr)oxides and oxalic acid have attracted a great deal of scientific attention in the application of organic pollutants degradation. However, the reaction mechanism is still unclear due to the complicated iron cycles and reactive oxygen species (ROS)generation. In this study, the in situ attenuated total reflectance-Fourier transform infrared spectroscopy was implemented to investigate the adsorption process and photochemical behavior of oxalic acid on the surface of ferrihydr...

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