Photoinduced Copper-Catalyzed Asymmetric Three-Component Radical 1,2-Azidooxygenation of 1,3-Dienes

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成果类型：

期刊论文

作者：

Li, Guo-Qing;Li, Zi-Qing;Jiang, Min;Zhang, Zhihan;Qian, Yu;...

通讯作者：

Chen, JR

作者机构：

[Li, Guo-Qing; Qian, Yu; Li, Zi-Qing; Xiao, Wen-Jing; Chen, Jia-Rong; Zhang, Zhihan; Chen, JR] Cent China Normal Univ, Coll Chem, Engn Res Ctr Photoenergy Utilizat Pollut Control &, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.

[Jiang, Min] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Hangzhou 310036, Peoples R China.

[Xiao, Wen-Jing; Chen, Jia-Rong; Chen, JR] Wuhan Inst Photochem & Technol, 7 North Bingang Rd, Wuhan 430083, Hubei, Peoples R China.

[Chen, Jia-Rong; Chen, JR] Gannan Normal Univ, Key Lab Organo Pharmaceut Chem Jiangxi Prov, Ganzhou 341000, Jiangxi, Peoples R China.

通讯机构：

[Chen, JR ] C

Cent China Normal Univ, Coll Chem, Engn Res Ctr Photoenergy Utilizat Pollut Control &, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.

Wuhan Inst Photochem & Technol, 7 North Bingang Rd, Wuhan 430083, Hubei, Peoples R China.

Gannan Normal Univ, Key Lab Organo Pharmaceut Chem Jiangxi Prov, Ganzhou 341000, Jiangxi, Peoples R China.

语种：

英文

关键词：

1,3-dienes;asymmetric C−O coupling;copper catalysis;radical azidooxygenation;visible light

期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN：

1433-7851

年：

2024

卷：

期：

页码：

e202405560

DOI：

10.1002/anie.202405560

基金类别：

National Natural Science Foundation of China [22171099, 92256301, 21820102003, 91956201]; National Key R&D Program of China [2023YFA1507203, 2022YFA1506100]; Cultivation Program of Wuhan Institute of Photochemistry and Technology [GHY2023KF001]; Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University [2021YB02]; Double-Thousand Talents Plan of Jiangxi Province [jxsq2023102004]

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

Radical-involved multicomponent difunctionalization of 1,3-dienes has recently emerged as a promising strategy for rapid synthesis of valuable allylic compounds in one-pot operation. However, the expansion of radical scope and enantiocontrol remain two major challenges. Herein, we describe an unprecedented photoinduced copper-catalyzed highly enantioselective three-component radical 1,2-azidooxygenation of 1,3-dienes with readily available azidobenziodazolone reagent and carboxylic acids. This mild protocol exhibits a broad substrate scope, high functional group tolerance, and exceptional cont...

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Photoinduced Copper-Catalyzed Asymmetric Three-Component Radical 1,2-Azidooxygenation of 1,3-Dienes

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