The development of green and sustainable methods for “effective” synthesis of fine chemicals is an important goal for synthetic organic chemists. Oxidative reactions are an important process in Nature and constitute one of the most fundamental chemical transformations in organic synthesis. This chapter highlights the recent advances of visible-light-mediated aerobic oxidation and oxygenation reactions. The amine motif is a kind of good electron donor due to the nitrogen atom possessing lone pair electron, and they are the most common reductiv...