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A novel H2O2-assisted method to fabricate Li4Ti5O12/TiO2 materials for high-performance energy storage

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成果类型:
期刊论文
作者:
Zhou, Jianqing;Zhu, Qiancheng;Hu, Hao;Chen, Wenjuan;Yu, Ying*
通讯作者:
Yu, Ying
作者机构:
[Zhu, Qiancheng; Hu, Hao; Chen, Wenjuan; Yu, Ying; Zhou, Jianqing] Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Hubei, Peoples R China.
通讯机构:
[Yu, Ying] C
Cent China Normal Univ, Coll Phys Sci & Technol, Inst Nanosci & Nanotechnol, Wuhan 430079, Hubei, Peoples R China.
语种:
英文
关键词:
Hydrogen peroxide;Spinel Li4Ti5O12;Commercial titania;Low temperature;Energy storage
期刊:
Electrochimica Acta
ISSN:
0013-4686
年:
2018
卷:
281
页码:
142-151
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21573085, 21377044]; Key Project of Natural Science Foundation of Hubei ProvinceNatural Science Foundation of Hubei Province [2015CFA037]; self-determined research funds of CCNU from the colleges' basic research and operation of MOE [CCNU18TS034]; "Hua Bo" Plan of Central China Normal University
机构署名:
本校为第一且通讯机构
院系归属:
物理科学与技术学院
摘要:
Spinel Li4Ti5O12 known as a "zero-strain" anode material for Li-ion battery has attracted much attention because of its superior safety and stability. Herein, we report a novel H2O2-assisted one-step hydrothermal method to synthesize different ratio Li4Ti5O12/TiO2 composites with the same amount of raw materials. For the first time, Li4Ti5O12 was prepared directly from commercial titania with the presence of H2O2, and different proportion Li4Ti5O12/TiO2 composites were fabricated only by adjusting the amount of H2O2. The reaction mechanism of the novel H2O2-assisted method was clearly investig...

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