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Tuning polyelectrolyte-graphene interaction for enhanced electrochemical nonenzymatic hydrogen peroxide sensing.

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成果类型:
期刊论文
作者:
Yan, Hongye;Wu, Yu;Luo, Xin;Jiao, Lei;Zhu, Chengzhou*;...
通讯作者:
Zhu, Chengzhou;Du, Dan
作者机构:
[Zhu, Chengzhou; Yan, Hongye; Wu, Yu; Jiao, Lei; Luo, Xin] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
[Du, Dan] Washington State Univ, Sch Mech & Mat Engn, POB 642920, Pullman, WA 99164 USA.
通讯机构:
[Zhu, Chengzhou] C
[Du, Dan] W
Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China.
Washington State Univ, Sch Mech & Mat Engn, POB 642920, Pullman, WA 99164 USA.
语种:
英文
关键词:
Charge transfer;Electrocatalysis;Graphene;Hydrogen peroxide detection;Polyelectrolytes
期刊:
Analytica Chimica Acta
ISSN:
0003-2670
年:
2019
卷:
1049
页码:
98-104
基金类别:
Recruitment Program of Global Youth Experts of China
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Herein, tuning polyelectrolyte-graphene interaction was demonstrated to enhance electrocatalytic activity for non-enzymatic hydrogen peroxide detection. The introduction of positively charged poly(diallyldimethylammonium chloride) (PDDA) onto graphene surface not only prevent the aggregation of graphene sheets through electrostatic repulsion but also create net positive charge on adjacent carbon atoms in the graphene due to the occurrence of the intermolecular charge transfer by virtue of the robust electron-withdrawing ability of PDDA. Notably...

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