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Visible Light Photocatalytic Radical Addition/Cyclization Reaction of o‐Vinyl‐N‐Alkoxybenzamides for Synthesis of CF3‐Containing Iminoisobenzofurans

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成果类型:
期刊论文
作者:
Liu, Zhi-Cheng;Zhao, Quan-Qing;Chen, Jun;Tang, Qian;Chen, Jia-Rong*;...
通讯作者:
Chen, Jia-Rong;Xiao, Wen-Jing
作者机构:
[Zhao, Quan-Qing; Chen, Jia-Rong; Xiao, WJ; Tang, Qian; Xiao, Wen-Jing; Chen, Jun; Liu, Zhi-Cheng] Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Hubei Int Sci & Technol Cooperat Base Pesticide &, Key Lab Pesticides & Chem Biol,Minist Educ,Coll C, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
[Xiao, Wen-Jing] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China.
通讯机构:
[Chen, JR; Xiao, WJ] C
[Xiao, Wen-Jing] S
Cent China Normal Univ, CCNU uOttawa Joint Res Ctr, Hubei Int Sci & Technol Cooperat Base Pesticide &, Key Lab Pesticides & Chem Biol,Minist Educ,Coll C, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China.
语种:
英文
关键词:
visible light;photoredox catalysis;iminoisobenzofurans;radical cascade;heterocycles
期刊:
ADVANCED SYNTHESIS & CATALYSIS
ISSN:
1615-4150
年:
2018
卷:
360
期:
11
页码:
2087-2092
基金类别:
We are grateful to the NNSFC (Nos. 21622201, 21472058, 21472057, and 21772053), the Distinguished Youth Foundation of Hubei Province (No. 2016CFA050), the Science and Technology Department of Hubei Province (2017AHB047), and CCNU (Nos. CCNU17TS0011 and CCNU16JCZX02) for support of this research. The Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019) is also appreciated.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A visible light-induced photocatalytic radical addition/cyclization reaction of o-vinyl-N-alkoxybenzamides has been accomplished for efficient synthesis of diversely functionalized CF3-containing iminoisobenzofurans. This external oxidant-free and mild protocol features ready availability of starting materials, excellent regioselectivity, good substrate scope and functional group tolerance. (Figure presented.). ...

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