Phenyl substituted indenylphosphine ruthenium complexes as catalysts for dehydrogenation of alcohols

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成果类型：

期刊论文

作者：

Yuan, Jia;Sun, Yue;Yu, Guang-Ao*;Zhao, Cui;She, Neng-Fang;...

通讯作者：

Yu, Guang-Ao

作者机构：

[Sun, Yue; Han, Zhi-Jun; Yuan, Jia; Yin, Jun; Yu, Guang-Ao; Zhao, Cui; Liu, Sheng-Hua; Huang, Peng-Shou] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.

[She, Neng-Fang] Nankai Univ, State Key Lab Elementoorgan Chem, Dept Chem, Tianjin 300071, Peoples R China.

[Mao, Shu-Lan] Hubei Univ, Minist Educ, Key Lab Green Preparat & Applicat Funct Mat, Wuhan 430062, Peoples R China.

通讯机构：

[Yu, Guang-Ao] C

Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China.

语种：

英文

期刊：

DALTON TRANSACTIONS

ISSN：

1477-9226

年：

2012

卷：

期：

页码：

10309-10316

DOI：

10.1039/c2dt30499f

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [20931006, 21072070, 21072071]; Program for Changjiang Scholars and Innovative Research Team in UniversityProgram for Changjiang Scholars & Innovative Research Team in University (PCSIRT) [IRT0953]; Program for Academic Leader in Wuhan Municipality [201271130441]; Science Foundation of Central China Normal University

机构署名：

本校为第一且通讯机构

院系归属：

化学学院

摘要：

Thermal treatment of (1H-inden-3-yl)dicyclohexylphosphinium tetrafluoroborate (1) and (3-mesityl-1H-inden-3-yl)dicyclohexylphosphinium tetrafluoroborate (3) with tBuONa followed by [(η 6-cymene) RuCl 2)] 2 in methanol gave the adduct {(η 6- cymene)RuCl 2[(1H-inden-3-yl)PCy 2]} (6) and {(η 6-cymene)RuCl 2[(3-mesityl-1H-inden-3-yl)PCy 2]} (7), respectively. Thermal treatment of (2-phenyl-1H-inden-3-yl) dicyclohexylphosphinium tetrafluoroborate (4) with tBuONa followed by [(η 6-cymene)RuCl 2)] 2 or RuCl 3·3H 2O in methanol gave {Ru[κ(P): (η...

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Phenyl substituted indenylphosphine ruthenium complexes as catalysts for dehydrogenation of alcohols

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