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Ball-milled zero-valent iron with formic acid for effectively removing Cu(II)-EDTA accomplished by EDTA ligands oxidative degradation and Cu(II) removal

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成果类型:
期刊论文
作者:
Zhang, Yuhang;Li, Donglei;She, Liang;Guo, Furong;Jia, Falong;...
通讯作者:
Jia, FL
作者机构:
[Zhang, Lizhi; Jia, Falong; Guo, Furong; Li, Donglei; Zhang, Yuhang; She, Liang; Ai, Zhihui; Liu, Xiao] Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
通讯机构:
[Jia, FL ] C
Cent China Normal Univ, Coll Chem, Wuhan 430079, Peoples R China.
语种:
英文
关键词:
Cu(II)-EDTA;Decomplexation;Ferrous formate shell;Oxidative degradation;Zero-valent iron
期刊:
Journal of Hazardous Materials
ISSN:
0304-3894
年:
2024
卷:
465
页码:
133009
基金类别:
CRediT authorship contribution statement Yuhang Zhang: Investigation, Data curation, Conceptualization, Methodology, Experimenting, Analysising, Visualization, Writing – original draft. Donglei Li: contributing to the assistance of characterization. Liang She: Methodology. Furong Guo: Methodology. Falong Jia: acquisition, Writing – review & editing, Project administration, Supervision. Lizhi Zhang: Supervision. Zhihui Ai: Supervision. Xiao Liu: Supervision.
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Heavy metal complexes in industrial wastewater are challenging to be removed by conventional methods arising from their stable chelating structure. In this study, zero-valent iron (ZVI) was ball-milled with tiny formic acid (FA), and the as-prepared sample (FA-ZVI(bm)) was attempted to eliminate a model heavy metal complex of Cu(II)-ethylenediaminetetraacetic acid (Cu(II)-EDTA). The addition of FA to ball-milling could dramatically enhance the performance of ball-milled ZVI (ZVI(bm)) towards Cu(II)-EDTA removal and increase the removal rate constant by 80 times. This conspicuous improvement of...

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