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Metallaphotoredox-Catalyzed Three-Component Couplings for Practical Synthesis of Ureas and Carbamates

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成果类型:
期刊论文
作者:
Koranteng, Ernest;Shu, Zhen-Cao;Liu, Yi-Yin;Yang, Qian;Shi, Bin;...
通讯作者:
Lu, Liang-Qiu;Xiao, WJ;Tan, F;Lu, LQ
作者机构:
[Yang, Qian; Lu, Liang-Qiu; Koranteng, Ernest; Shi, Bin; Liu, Yi-Yin; Wu, Qiang-Xian; Xiao, Wen-Jing; Lu, LQ; Xiao, WJ] Cent China Normal Univ, Coll Chem, Engn Res Ctr Photoenergy Utilizat Pollut Control &, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
[Shu, Zhen-Cao] Wuhan Youji Ind Co Ltd, 1 2nd Chem Rd, Wuhan 430082, Hubei, Peoples R China.
[Tan, Fen] Hubei Univ Educ, Sch Chem & Life Sci, Hubei Key Lab Purificat & Applicat Plant Anticanc, Wuhan 430205, Hubei, Peoples R China.
[Lu, Liang-Qiu; Lu, LQ] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China.
[Lu, Liang-Qiu; Lu, LQ] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China.
通讯机构:
[Lu, LQ ; Lu, LQ; Xiao, WJ ] C
[Tan, F ] H
Cent China Normal Univ, Coll Chem, Engn Res Ctr Photoenergy Utilizat Pollut Control &, Minist Educ, 152 Luoyu Rd, Wuhan 430079, Hubei, Peoples R China.
Hubei Univ Educ, Sch Chem & Life Sci, Hubei Key Lab Purificat & Applicat Plant Anticanc, Wuhan 430205, Hubei, Peoples R China.
Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China.
语种:
英文
关键词:
Cross-coupling;Nickel;Photoredox catalysis;Three-component reaction;Ureas;Carbamates
期刊:
中国化学
ISSN:
1001-604X
年:
2024
卷:
42
期:
3
页码:
264-270
基金类别:
We are grateful to the National Natural Science Foundation of China (Nos. 22271113, 92256301, 21822103, 91956201, 21820102003 and 21602052), the Natural Science Foundation of Hubei Province (No. 2022CFB413) and the fund from Central China Normal University [22271113, 92256301, 21822103, 91956201, 21820102003, 21602052]; National Natural Science Foundation of China [2022CFB413]; Natural Science Foundation of Hubei Province; Central China Normal University
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
Highly efficient three‐component coupling of organic halides, sodium cyanate and amines or alcohols was achieved with a nickel/photoredox dual catalysis system. Significant N‐containing functional compounds, ureas and carbamates, were produced under green and sustainable conditions. Comprehensive Summary Ureas are widely used in drugs, materials and catalysts because of their diamide structure, which can form strong hydrogen bonds. Therefore, it is of great scientific significance to develop efficient and green methods for the synthesis of ur...

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