National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21472056, 21272085]
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
A novel strategy has been developed for the direct synthesis of 2-aroyl-3-hydroxy-4-iodonaphthalenes from easily available (Z)-2-(hetero)arylidene-1-(hetero)arylbutane-1,3-diones in the presence of copper(ii) oxide and iodine. This domino process involves consecutive methyl iodination/carbon-carbon double bond isomerization/6π-electrocyclization/aromatization/arene iodinatio...