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Recent advances in radical‐mediated transformations of 1,3‐dienes

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成果类型:
期刊论文
作者:
Wang, Peng-Zi;Xiao, Wen-Jing;Chen, Jia-Rong
通讯作者:
Chen, JR
作者机构:
[Xiao, Wen-Jing; Chen, Jia-Rong; Wang, Peng-Zi; Chen, JR] Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticides & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
[Chen, Jia-Rong; Chen, JR] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China.
通讯机构:
[Chen, JR ] C
Cent China Normal Univ, Coll Chem, CCNU uOttawa Joint Res Ctr, Key Lab Pesticides & Chem Biol,Minist Educ, Wuhan 430079, Hubei, Peoples R China.
Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China.
语种:
英文
关键词:
1,3-Dienes;Photoredox catalysis;Radical difunctionalization;Radical transformations;Transition metal catalysis
关键词(中文):
自由基反应;3-二烯;自由基双官能化;过渡金属催化;光氧化还原催化
期刊:
催化学报
ISSN:
0253-9837
年:
2022
卷:
43
期:
3
页码:
548-557
基金类别:
This work was supported by the National Natural Science Foundation of China (91856119, 21971081, 21820102003, 91956201), the Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University (2021YB02), the Excellent Doctoral Dissertation Cultivation Grant to Peng-Zi Wang from CCNU, and the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019).
机构署名:
本校为第一且通讯机构
院系归属:
化学学院
摘要:
1,3-Dienes are a class of easily accessible and versatile feedstock chemicals that can participate in a wide range of reactions to facilitate the synthesis of various valuable allylic compounds. In the past decades, radical methodology has emerged as a powerful tool for organic synthesis by virtue of the fact that diverse highly reactive radical species can usually be generated under mild, neutral and controlled conditions, and allow for rapid generation of molecular complexity. In this review, we critically illustrate the recent advances in th...
摘要(中文):
有机自由基化学的发展可追溯到110多年前.起初,高活性的自由基中间体被认为是难以控制且不可预测的物种,往往导致反应变得杂乱无章,这种误解导致该领域的研究没有得到足够的重视.为了发展高效、高选择性且符合绿色化学要求的化学转化,合成化学家们一直致力于开发新颖的催化体系和反应试剂,而自由基化学因其独特的反应性质和巨大的发展潜力也逐渐引起人们的广泛关注.与离子型物种相比,自由基物种在拓展反应类型、提升反应兼容性以及快速构筑分子复杂性方面具有显著优势.伴随着这一领域的快速发展,自由基化学已逐渐取得了许多不错的突破和进展.如今,自由基反应已经作为有机合成中一类重要反应,在化...

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